Scientific Journal Of King Faisal University: Basic and Applied Sciences
Scientific Journal of King Faisal University: Basic and Applied Sciences
Enhancing the Surface Properties of Additively and Conventionally Manufactured 18Ni300 Maraging Steel through Gas Nitriding
(Syed Sohail and B Chandra Mohan Reddy)Abstract
The aim of this study was to investigate the differences in microstructure and microhardness between additively manufactured (AM) and conventionally manufactured (CM) 18Ni300 maraging steel, after subjecting samples to a low-temperature gas nitriding treatment in the solution-annealed condition. A microstructural characterization revealed equiaxed grains in CM specimens, whereas AM specimens contained irregular martensitic laths, reflecting their distinct solidification and thermal histories. Nitriding at 360°C resulted in effective case depths of approximately 60 µm for AM and 55 µm for CM specimens, values that were attributed to the enhanced nitrogen diffusivity and reduced competition with intermetallic precipitate formation at this temperature. The surface microhardness reached 1115±15 HV0.01 for AM and 1090±15 HV0.01 for CM, with a gradual decrease toward core hardness values of 560±6 HV0.01 and 548±6 HV0.01, respectively. The superior hardening response for the AM specimens is associated with their columnar grain morphology and higher dislocation density, which facilitate nitrogen trapping and strengthening. These findings demonstrate that when combined with low-temperature nitriding, additive manufacturing offers a promising method of achieving enhanced surface properties in maraging steel components intended for high-performance tool industry applications.
KEYWORDS
Metal 3D printing, microhardness, microstructure, surface engineering, strength steel, surface properties
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References
Andani, N.T., Safaei, K., Poorganji, B. and Elahini, M. (2023). Rotating scanning strategies for tailoring crystallographic texture of additively manufactured NiTi shape memory alloy. Materials Letters, 340(12), 134156. DOI: 10.1016/j.matlet.2023.134156.
Ansell, T.Y., Ricks, J.P., Park, C., Tipper, C.S. and Luhrs, C.C. (2020). Mechanical Properties of 3D-Printed Maraging Steel Induced by Environmental Exposure. Metals, 10(2), 218. DOI: 10.3390/met10020218.
Bai, Y., Yang, Y., Wang, D. and Zhang, M. (2017). Influence mechanism of parameters process and mechanical properties evolution mechanism of maraging steel 300 by selective laser melting. Materials Science and Engineering: A, 703(n/a), 116–23. DOI: 10.1016/j.msea.2017.06.033.
Bai, Y., Zhao, C., Wang D. and Wang, H. (2022) Evolution mechanism of surface morphology and internal hole defect of 18Ni300 maraging steel fabricated by selective laser melting, Journal of Materials Processing Technology, 299(n/a), 117328. DOI: 10.1016/j.jmatprotec.2021.117328.
Di Angelo, L., Di Stefano, P. and Guardiani, E. (2020). Search for the optimal build direction in additive manufacturing technologies: A review. Journal of Manufacturing and Materials Processing, 4(3), 71. DOI: 10.3390/jmmp4030071.
Fayazfar, H., Salarian, M., Rogalsky, A., Sarker, D., Russo, P., Paserin, V. and Toyserkani, E. (2018). A critical review of powder-based additive manufacturing of ferrous alloys: Process parameters, microstructure and mechanical properties. Materials and Design, 144(n/a), 98–128. DOI: 10.1016/j.matdes.2018.02.018.
Fonseca, D., Feitosa, A.M., Melo, F., de Carvalho, L., Lesley, R. and Padilha, A. (2021). A short review on ultra-high-strength maraging steels and future perspectives. Materials Research, 24(n/a), 20200470. DOI: 10.1590/1980-5373-MR-2020-0470.
Funch, C.V., Christiansen, T.L. and Somers, M.A.J. (2022). Gaseous nitriding of additively manufactured maraging steel; nitriding kinetics and microstructure evolution. Surface and Coatings Technology, 432(n/a), 128055. DOI: 10.1016/j.surfcoat.2021.128055.
Geiger, F., Kunze, K. and Etter, T. (2016). Tailoring the texture of IN738LC processed by selective laser melting (SLM) by specific scanning strategies. Materials Science and Engineering: A, 661(n/a), 240–46. DOI: 10.1016/j.msea.2016.03.036.
Godec, M., Podgornik, B., Kocijan, A., Donik, C. and Balantic D.A.S. (2021). Use of plasma nitriding to improve the wear and corrosion resistance of 18Ni-300 maraging steel manufactured by selective laser melting. Scientific Reports, 11(n/a), 3277. DOI: 10.1038/s41598-021-82572-y.
Godec, M., Ruiz-Zepeda, F., Podgornik, B., Donik, C., Kocijan, A. and Skobir Balantic, D.A. (2022). The influence of the plasma nitriding temperature on the microstructure evolution and surface properties of additive-manufactured 18Ni300 maraging steel. Surface and Coatings Technology, 433(n/a), 128089. DOI: 10.1016/j.surfcoat.2022.128089.
Gong, H., Rafi, K., Gu, H., Ram, J., Starr, T. and Stucker, B. (2015). Influence of defects on mechanical properties of Ti–6Al–4V components produced by selective laser melting and electron beam melting. Materials and Design, 86(n/a), 545–54. DOI: 10.1016/j.matdes.2015.07.147.
Guo, L. (2024). Characterization of Microstructure and High Strain Rate Deformation Response of C250 Maraging Steel Fabricated by Directed Energy Deposition Process. PhD Thesis, University of Manitoba, Canada.
Guo, L., Zhang, L., Andersson, J. and Ojo, O. (2022). Additive manufacturing of 18% nickel maraging steels: Defect, structure and mechanical properties: A review, Journal of Materials Science and Technology, 120(n/a), 227–52. DOI: 10.1016/j.jmst.2021.10.056.
Hall, A. and Slunder, C. (1968). The Metallurgy, Behavior, and Application of the 18-Percent Nickel Maraging Steels, 20000828 057, NASA 36. Available at: https://apps.dtic.mil/sti/tr/pdf/ADA382105.pdf.
Herzog, D., Seyda, V., Wycisk, E. and Emmelmann, C. (2016). Additive manufacturing of metals. Acta Materialia, 117(n/a), 371–92. DOI: 10.1016/j.actamat.2016.07.019.
Hojjatzadeh, S.M.H., Parab, N.D., Guo, Q., Zhao, C., Qu, M., Escano, L.I., Fezzaa, K., Sun, T. and Chen, L. (2020). Direct observation of pore formation mechanisms during LPBF additive manufacturing process and high energy density laser welding. International Journal of Machine Tools and Manufacture, 153(n/a), 103555. DOI: 10.1016/j.ijmachtools.2020.103555.
Hong, Y., Dong, D.D., Lin, S.S., Wang, W., Cai, X.Y. and Zhuang, L.Z. (2021). Improving surface mechanical properties of the selective laser melted 18Ni300 maraging steel via plasma nitriding. Surface and Coatings Technology, 406(n/a), 126675. DOI: 10.1016/j.surfcoat.2020.126675\.
Hosmani, S.S., Schacherl, R.E. and Mittemeijer, E.J. (2007). Kinetics of nitriding Fe-2 Wt Pct V alloy: Mobile and immobile excess nitrogen. Metallurgical and Materials Transactions A, 38(n/a), 7–16. DOI: 10.1007/s11661-006-9046-9.
Hu, Z., Yang, Z., Du, Z., Wu, J., Dong, J., Wang, H. and Ma, Z., (2022). Effect of scanning strategy on the anisotropy in microstructure and properties of Cu-Cr-Zr alloy manufactured by laser powder bed fusion. Journal of Alloys and Compounds, 920(n/a), 165957. DOI: 10.1016/j.jallcom.2022.165957.
Jagle, E.A., Sheng, Z., Kurnsteiner, P., Ocylok, S., Weisheit, A. and Raabe, D. (2017). Comparison of maraging steel micro- and nanostructure produced conventionally and by laser additive manufacturing. Materials, 10(1), 8. DOI: 10.3390/ma10010008.
Jia, H., Sun, H., and Wang, H., Wu, Y. and Wang, H. (2021). Scanning strategy in selective laser melting (SLM): A review, The International Journal of Advanced Manufacturing Technology, 113(n/a), 2413–35. DOI: 10.1007/s00170-021-06810-3.
Kim, D., Kim, T., Ha, K., Oak, J., Jeon, J.B., Park, Y. and Lee, W. (2020). Effect of Heat Treatment Condition on Microstructural and Mechanical Anisotropies of Selective Laser Melted Maraging 18Ni-300 Steel. Metals, 10(3), 410. DOI: 10.3390/met10030410.
Li, K., Yang, T., Gong, N., Wu, J., Wu, X., Zhang D.Z. and Murr, L.E. (2023). Additive manufacturing of ultra-high strength steels: A review. Journal of Alloys and Compounds, 965(n/a), 171390. DOI: 10.1016/j.jallcom.2023.171390.
Ma, Y., Gao, Y., Zhao, L., Li, D. and Men, Z. (2022). Optimization of process parameters and analysis of microstructure and properties of 18Ni300 by selective laser melting. Materials, 15(n/a), 4757. DOI: 10.3390/ma15144757.
Marattukalam, J.J., Karlsson, D., Pacheco, V., Beran, P., Wiklund, U., Jansson, U.,Hjorvarsson, B. and Sahlberg, M., (2020). The effect of laser scanning strategies on texture, mechanical properties, and site-specific grain orientation in selective laser melted 316L SS. Materials and Design, 193(n/a), 108852. DOI: 10.1016/j.matdes.2020.108852.
Mittemeijer, E.J. and Somers, M.A. (2015). Thermochemical surface engineering of steels. Woodhead Publishing, Cambridge.
Peng, T. and Chen, C. (2018). Influence of energy density on energy demand and porosity of 316L stainless steel fabricated by selective laser melting. International Journal of Precision Engineering and Manufacturing- Green Technology, 5(n/a), 55–62. DOI: 10.1007/s40684-018-0006-9.
Sanaei, N. and Fatemi, A. (2020). Defects in additive manufactured metals and their effect on fatigue performance: A state-of-the-art review, Progress in Materials Science, 117(n/a), 100724. DOI: 10.1016/j.pmatsci.2020.100724.
Sohail, S. and Reddy, B.C.M. (2025a). Experimental investigation on end milling behavior of additively and conventionally manufactured 18Ni300 maraging steel, proceedings of the international conference on advanced materials, manufacturing and sustainable development (ICAMMSD 2024). Atlantis Press, n/a(n/a), 525–42. DOI: 10.2991/978-94-6463-662-8_42.
Sohail, S. and Reddy, B.C.M. (2025b). Optimizing surface roughness in end milling of additively and conventionally manufactured components of 18Ni300 maraging steel with minimum quantity lubrication. Engineering Research Express, 7(1), 015503. DOI: 10.1088/2631-8695/ada22e.
Somers, M.A.J., Lankreijer, R.M. and Mittemeijer, E.J. (1989). Excess nitrogen in the ferrite matrix of nitrided binary iron-based alloys. Philosophical Magazine A, 59(2), 353–78. DOI: 10.1080/01418618908205064.
Song, J., Tang, Q., Chen, H., Zhang, Z., Feng, Q., Zhao, M., Ma, S. and Setchi, R. (2022). Laser powder bed fusion of high-strength maraging steel with concurrently enhanced strength and ductility after heat treatments. Materials Science and Engineering: A, 854(n/a), 143818. DOI: 10.1016/j.msea.2022.143818.
Song, J., Tang, Q., Feng, Q., Ma, S., Setchi, R., Liu, Y., Han, Q., Fan, X. and Zhang, M. (2019). Effect of heat treatment on microstructure and mechanical behaviours of 18Ni-300 maraging steel manufactured by selective laser melting. Optics and Laser Technology, 120(n/a), 105725. DOI: 10.1016/j.optlastec.2019.105725.
Takata, N., Nishida, R., Suzuki, A., Kobashi, M. and Kato, M. (2018). Crystallographic features of microstructure in maraging steel fabricated by selective laser melting. Metals, 8(6), 440. DOI: 10.3390/met8060440.
Tan, C., Zhou, K., Ma, W., Zhang, P., Liu, M. and Kuang, T. (2017). Microstructural evolution, nanoprecipitation behavior and mechanical properties of selective laser melted high-performance grade 300 maraging steel. Materials and Design, 134(n/a), 23–34. DOI: 10.1016/j.matdes.2017.08.026.
Vasques, C.M.A., Cavadas, A.M.S. and Abrantes, J.C.C. (2025). Technology overview and investigation of the quality of a 3D-printed maraging steel demonstration part. Materials Science in Additive Manufacturing, 4(2), 025040002. DOI: 10.36922/MSAM025040002.
Vishwakarma, J., Chattopadhyay, K. and Santhi Srinivas, N.C. (2020). Effect of build orientation on microstructure and tensile behavior of selectively laser melted M300 maraging steel. Materials Science and Engineering: A, 798(n/a), 140130, DOI: 10.1016/j.msea.2020.140130.
Zheng, Z., Sun, B. and Mao, L. (2024). Effect of scanning strategy on the manufacturing quality and performance of printed 316l stainless steel using SLM process. Materials, 17(5), 1189. DOI: 10.3390/ma17051189.